| 1801 | Lytchett Minster School | 1,590 pupils | State · Day · 6th | Poole, South West | — |
| 1802 | The Hazeley Academy | 1,590 pupils | Academy · Day · 6th | Milton Keynes, South East | — |
| 1803 | Brentside High School | 1,589 pupils | State · Day · 6th | London, London | — |
| 1804 | St Robert of Newminster Catholic School and Sixth Form College, Washington | 1,588 pupils | Academy · Day · 6th | Washington, North East | — |
| 1805 | Aldridge School - A Science College | 1,585 pupils | Academy · Day · 6th | Walsall, West Midlands | — |
| 1806 | Tring School | 1,584 pupils | Academy · Day · 6th | Tring, East of England | — |
| 1807 | Paignton Academy | 1,582 pupils | Academy · Day | Paignton, South West | — |
| 1808 | Elthorne Park High School | 1,580 pupils | State · Day · 6th | London, London | — |
| 1809 | Thornleigh Salesian College | 1,576 pupils | State · Day · 6th | Bolton, North West | — |
| 1810 | Minsthorpe Community College | 1,575 pupils | Academy · Day · 6th | Pontefract, Yorkshire and the Humber | — |
| 1811 | The Gilberd School | 1,574 pupils | Academy · Day | Colchester, East of England | — |
| 1812 | Imberhorne School | 1,573 pupils | State · Day · 6th | East Grinstead, South East | — |
| 1813 | Bourne Academy | 1,571 pupils | Academy · Day · 6th | Bourne, East Midlands | — |
| 1814 | Plantsbrook School | 1,570 pupils | Academy · Day · 6th | Sutton Coldfield, West Midlands | — |
| 1815 | North Chadderton School | 1,569 pupils | Academy · Day · 6th | Oldham, North West | — |
| 1816 | Highcliffe School | 1,565 pupils | Academy · Day · 6th | Christchurch, South West | — |
| 1817 | Soar Valley College | 1,564 pupils | Academy · Day | Leicester, East Midlands | — |
| 1818 | West Hatch High School | 1,564 pupils | Academy · Day · 6th | Chigwell, East of England | — |
| 1819 | St Mary's Catholic High School | 1,561 pupils | State · Day · 6th | Manchester, North West | — |
| 1820 | The Appleton School | 1,561 pupils | Academy · Day · 6th | Benfleet, East of England | — |
| 1821 | Hardenhuish School | 1,559 pupils | Academy · Day · 6th | Chippenham, South West | — |
| 1822 | Lutterworth College | 1,559 pupils | Academy · Day · 6th | Lutterworth, East Midlands | — |
| 1823 | Towers School and Sixth Form Centre | 1,559 pupils | Academy · Day · 6th | Ashford, South East | — |
| 1824 | Ashlawn School | 1,558 pupils | Academy · Day · 6th | Rugby, West Midlands | — |
| 1825 | Q3 Academy Tipton | 1,558 pupils | Academy · Day · 6th | Tipton, West Midlands | — |