| 1676 | The Thomas Hardye School | 2,051 pupils | Academy · Day · 6th | Dorchester, South West | — |
| 1677 | Hall Cross Academy | 2,038 pupils | Academy · Day · 6th | Doncaster, Yorkshire and the Humber | — |
| 1678 | Rushcliffe Spencer Academy | 2,032 pupils | Academy · Day · 6th | Nottingham, East Midlands | — |
| 1679 | Cramlington Learning Village | 2,021 pupils | Academy · Day · 6th | Cramlington, North East | — |
| 1680 | King's Academy Bay House | 2,003 pupils | Academy · Day · 6th | Gosport, South East | — |
| 1681 | Kingsbury High School | 1,997 pupils | Academy · Day · 6th | London, London | — |
| 1682 | The Cardinal Wiseman Catholic School | 1,994 pupils | State · Day · 6th | Greenford, London | — |
| 1683 | Bingley Grammar School | 1,966 pupils | State · Day · 6th | Bingley, Yorkshire and the Humber | — |
| 1684 | Comberton Village College | 1,962 pupils | Academy · Day · 6th | Cambridge, East of England | — |
| 1685 | Greenshaw High School | 1,961 pupils | Academy · Day · 6th | Sutton, London | — |
| 1686 | Springwood High School | 1,957 pupils | Academy · Day · 6th | King's Lynn, East of England | — |
| 1687 | St Bede's School | 1,952 pupils | State · Day · 6th | Redhill, South East | — |
| 1688 | Copleston High School | 1,937 pupils | Academy · Day · 6th | Ipswich, East of England | — |
| 1689 | Alperton Community School | 1,924 pupils | Academy · Day · 6th | Wembley, London | — |
| 1690 | Penistone Grammar School | 1,922 pupils | State · Day · 6th | Sheffield, Yorkshire and the Humber | — |
| 1691 | Swanshurst School | 1,920 pupils | Academy · Day · 6th | Birmingham, West Midlands | — |
| 1692 | Horizon Community College | 1,916 pupils | Academy · Day | Barnsley, Yorkshire and the Humber | — |
| 1693 | Stratford Upon Avon School | 1,904 pupils | Academy · Day · 6th | Stratford-upon-Avon, West Midlands | — |
| 1694 | Weald of Kent Grammar School | 1,902 pupils | Grammar · Day · 6th | Tonbridge, South East | — |
| 1695 | St Paul's Catholic School | 1,886 pupils | State · Day · 6th | Milton Keynes, South East | — |
| 1696 | Shenley Brook End School | 1,883 pupils | Academy · Day · 6th | Milton Keynes, South East | — |
| 1697 | Garforth Academy | 1,880 pupils | Academy · Day · 6th | Leeds, Yorkshire and the Humber | — |
| 1698 | Poole High School | 1,875 pupils | Academy · Day · 6th | Poole, South West | — |
| 1699 | Parrs Wood High School | 1,867 pupils | Academy · Day · 6th | Manchester, North West | — |
| 1700 | The Crompton House Church of England Academy | 1,859 pupils | Academy · Day · 6th | Oldham, North West | — |