| 76 | The Thomas Hardye School Period 202425 | 49.8 | Academy · Day · 6th | Dorchester, South West | — |
| 77 | Chew Valley School Period 202425 | 49.8 | Academy · Day · 6th | Bristol, South West | — |
| 78 | Malmesbury School Period 202425 | 49.8 | Academy · Day · 6th | Malmesbury, South West | Outstanding |
| 79 | The Blue School Period 202425 | 49.7 | Academy · Day · 6th | Wells, South West | — |
| 80 | Camborne Science and International Academy Period 202425 | 49.7 | Academy · Day · 6th | Camborne, South West | Good |
| 81 | Kingsbridge Academy Period 202425 | 49.6 | Academy · Day · 6th | Kingsbridge, South West | Good |
| 82 | The Bishop of Winchester Academy Period 202425 | 49.6 | Academy · Day · 6th | Bournemouth, South West | Good |
| 83 | Penryn College Period 202425 | 49.2 | Academy · Day | Penryn, South West | — |
| 84 | Coombe Dean School Period 202425 | 49.2 | Academy · Day · 6th | Plymouth, South West | Good |
| 85 | Penair School Period 202425 | 49.1 | Academy · Day | Truro, South West | — |
| 86 | Farmor's School Period 202425 | 49.1 | Academy · Day · 6th | Fairford, South West | Good |
| 87 | Nova Hreod Academy Period 202425 | 49.1 | Academy · Day | Swindon, South West | — |
| 88 | Henley Bank High School Period 202425 | 49.0 | Academy · Day · 6th | Gloucester, South West | Good |
| 89 | Gordano School Period 202425 | 49.0 | Academy · Day · 6th | Bristol, South West | Good |
| 90 | Fairfield High School Period 202425 | 48.9 | Academy · Day | Bristol, South West | — |
| 91 | Haygrove School Period 202425 | 48.8 | Academy · Day | Bridgwater, South West | Good |
| 92 | The Kings of Wessex Academy Period 202425 | 48.7 | Academy · Day · 6th | Cheddar, South West | — |
| 93 | Chosen Hill School Period 202425 | 48.6 | Academy · Day · 6th | Gloucester, South West | — |
| 94 | Newquay Tretherras Period 202425 | 48.4 | Academy · Day · 6th | Newquay, South West | — |
| 95 | The Roseland Academy Period 202425 | 48.3 | Academy · Day | Truro, South West | — |
| 96 | Falmouth School Period 202425 | 48.3 | Academy · Day · 6th | Falmouth, South West | — |
| 97 | Cirencester Kingshill School Period 202425 | 48.2 | Academy · Day | Cirencester, South West | — |
| 98 | Bradon Forest School Period 202425 | 48.1 | Academy · Day | Swindon, South West | Good |
| 99 | Cheltenham Bournside School and Sixth Form Centre Period 202425 | 48.1 | Academy · Day · 6th | Cheltenham, South West | Good |
| 100 | Launceston College Period 202425 | 48.0 | Academy · Day · 6th | Launceston, South West | Good |