| 26 | King Edward VI Camp Hill School for Girls Period 202425 | 55.1% | Grammar · Day · 6th | Birmingham, West Midlands | Outstanding |
| 27 | Altrincham Grammar School for Boys Period 202425 | 54.7% | Grammar · Day · 6th | Altrincham, North West | Outstanding |
| 28 | Langley Grammar School Period 202425 | 54.1% | Grammar · Day · 6th | Langley, South East | Outstanding |
| 29 | Michaela Community School Period 202425 | 54.1% | Free School · Day · 6th | London, London | — |
| 30 | King Edward VI School Period 202425 | 53.8% | Grammar · Day · 6th | Stratford-upon-Avon, West Midlands | Outstanding |
| 31 | Royal Latin School Period 202425 | 52.1% | Grammar · Day · 6th | Buckingham, South East | Good |
| 32 | St Michael's Catholic Grammar School Period 202425 | 52.0% | Grammar · Day · 6th | London, London | Outstanding |
| 33 | Kendrick School Period 202425 | 51.4% | Grammar · Day · 6th | Reading, South East | Outstanding |
| 34 | Dame Alice Owen's School Period 202425 | 50.9% | Academy · Day · 6th | Potters Bar, East of England | Outstanding |
| 35 | Ralph Thoresby School Period 202425 | 50.0% | State · Day · 6th | Leeds, Yorkshire and the Humber | — |
| 36 | The JCB Academy Period 202425 | 50.0% | Free School · Day · 6th | Rocester, West Midlands | Good |
| 37 | The Community College, Bishop's Castle Period 202425 | 49.5% | State · Day | Bishops Castle, West Midlands | — |
| 38 | The Royal Grammar School, High Wycombe Period 202425 | 47.7% | Grammar · Boarding · 6th | High Wycombe, South East | Good |
| 39 | The Lakes School Period 202425 | 45.5% | State · Day · 6th | Windermere, North West | Good |
| 40 | Bishop Vesey's Grammar School Period 202425 | 45.2% | Grammar · Day · 6th | Sutton Coldfield, West Midlands | Outstanding |
| 41 | Sir William Borlase's Grammar School Period 202425 | 44.4% | Grammar · Day · 6th | Marlow, South East | Outstanding |
| 42 | Colchester County High School for Girls Period 202425 | 44.0% | Grammar · Day · 6th | Colchester, East of England | Outstanding |
| 43 | Holmleigh Park High School Period 202425 | 43.8% | Academy · Day · 6th | Gloucester, South West | Good |
| 44 | Chesham Grammar School Period 202425 | 43.3% | Grammar · Day · 6th | Chesham, South East | — |
| 45 | Wolverhampton Girls' High School Period 202425 | 43.2% | Grammar · Day · 6th | Wolverhampton, West Midlands | Outstanding |
| 46 | West London Free School Period 202425 | 42.7% | Free School · Day · 6th | London, London | Good |
| 47 | Westcliff High School for Boys Academy Period 202425 | 42.3% | Grammar · Day · 6th | Westcliff-on-Sea, East of England | Outstanding |
| 48 | Wallington High School for Girls Period 202425 | 41.5% | Grammar · Day · 6th | Wallington, London | — |
| 49 | Camborne Science and International Academy Period 202425 | 41.4% | Academy · Day · 6th | Camborne, South West | Good |
| 50 | Christ's Church of England Comprehensive Secondary School Period 202425 | 41.1% | State · Day · 6th | Richmond, London | — |