| 1 | Pate's Grammar School Period 202425 | 99.3% | Grammar · Day · 6th | Cheltenham, South West | Outstanding |
| 2 | Colyton Grammar School Period 202425 | 98.7% | Grammar · Day · 6th | Colyton, South West | Outstanding |
| 3 | The Crypt School Period 202425 | 98.0% | Grammar · Day · 6th | Gloucester, South West | Outstanding |
| 4 | Churston Ferrers Grammar School Academy Period 202425 | 95.9% | Grammar · Day · 6th | Brixham, South West | Good |
| 5 | Ivybridge Community College Period 202425 | 71.6% | Academy · Day · 6th | Ivybridge, South West | Good |
| 6 | Redland Green School Period 202425 | 68.7% | Academy · Day · 6th | Bristol, South West | Good |
| 7 | Balcarras School Period 202425 | 66.5% | Academy · Day · 6th | Cheltenham, South West | — |
| 8 | Bristol Free School Period 202425 | 66.3% | Free School · Day · 6th | Bristol, South West | Good |
| 9 | St Bede's Catholic College Period 202425 | 65.4% | Academy · Day · 6th | Bristol, South West | — |
| 10 | Ralph Allen School Period 202425 | 63.0% | Academy · Day · 6th | Bath, South West | — |
| 11 | Twynham School Period 202425 | 62.4% | Academy · Day · 6th | Christchurch, South West | Good |
| 12 | The Ridgeway School & Sixth Form College Period 202425 | 61.9% | Academy · Day · 6th | Swindon, South West | Good |
| 13 | St Mary Redcliffe and Temple School Period 202425 | 61.6% | State · Day · 6th | Bristol, South West | — |
| 14 | Chulmleigh Community College Period 202425 | 61.4% | Academy · Day | Chulmleigh, South West | — |
| 15 | St Peter's Church of England Aided School Period 202425 | 61.2% | State · Day | Exeter, South West | — |
| 16 | Braunton Academy Period 202425 | 61.2% | Academy · Day | Braunton, South West | — |
| 17 | Yate Academy Period 202425 | 60.4% | Academy · Day · 6th | Yate, South West | Good |
| 18 | Bristol Cathedral Choir School Period 202425 | 60.1% | Academy · Day · 6th | Bristol, South West | Good |
| 19 | John Cabot Academy Period 202425 | 60.0% | Academy · Day · 6th | Bristol, South West | — |
| 20 | Dene Magna School Period 202425 | 59.9% | Academy · Day · 6th | Mitcheldean, South West | — |
| 21 | Katharine Lady Berkeley's School Period 202425 | 59.9% | Academy · Day · 6th | Wotton-under-Edge, South West | — |
| 22 | Winterbourne Academy Period 202425 | 58.7% | Academy · Day · 6th | Bristol, South West | Good |
| 23 | St Laurence School Period 202425 | 58.4% | Academy · Day · 6th | Bradford-on-Avon, South West | — |
| 24 | The Castle School Period 202425 | 58.3% | Academy · Day · 6th | Bristol, South West | — |
| 25 | Trinity Academy Period 202425 | 57.7% | Free School · Day · 6th | Bristol, South West | Good |