| 1 | Dame Alice Owen's School Period 202425 | 87.5% | Academy · Day · 6th | Potters Bar, East of England | Outstanding |
| 2 | St Clement Danes School Period 202425 | 83.9% | Academy · Day · 6th | Rickmansworth, East of England | Outstanding |
| 3 | Chesterton Community College Period 202425 | 83.7% | Academy · Day · 6th | Cambridge, East of England | — |
| 4 | Sandringham School Period 202425 | 83.5% | Academy · Day · 6th | St Albans, East of England | Outstanding |
| 5 | Parmiter's School Period 202425 | 80.8% | Academy · Day · 6th | Watford, East of England | Outstanding |
| 6 | Rickmansworth School Period 202425 | 80.5% | Academy · Day · 6th | Rickmansworth, East of England | Outstanding |
| 7 | Parkside Community College Period 202425 | 78.1% | Academy · Day | Cambridge, East of England | — |
| 8 | St George's School Period 202425 | 76.6% | Academy · Boarding · 6th | Harpenden, East of England | — |
| 9 | Sir John Lawes School Period 202425 | 75.5% | Academy · Day · 6th | Harpenden, East of England | Outstanding |
| 10 | Yavneh College Period 202425 | 75.0% | Academy · Day · 6th | Borehamwood, East of England | Good |
| 11 | St Bede's Inter-Church School Period 202425 | 73.9% | Academy · Day | Cambridge, East of England | Outstanding |
| 12 | Beaumont School Period 202425 | 73.6% | Academy · Day · 6th | St Albans, East of England | — |
| 13 | Hockerill Anglo-European College Period 202425 | 72.5% | Academy · Boarding · 6th | Bishop's Stortford, East of England | Good |
| 14 | Hethersett Academy Period 202425 | 71.3% | Academy · Day | Norwich, East of England | — |
| 15 | Ashlyns School Period 202425 | 70.7% | State · Day · 6th | Berkhamsted, East of England | Good |
| 16 | Notre Dame High School, Norwich Period 202425 | 69.3% | Academy · Day · 6th | Norwich, East of England | Good |
| 17 | Becket Keys Church of England Free School Period 202425 | 68.6% | Free School · Day · 6th | Brentwood, East of England | — |
| 18 | Debenham High School Period 202425 | 68.1% | Academy · Day | Stowmarket, East of England | Good |
| 19 | Harris Academy Chafford Hundred Period 202425 | 68.1% | Academy · Day · 6th | Grays, East of England | Outstanding |
| 20 | Davenant Foundation School Period 202425 | 67.8% | Academy · Day · 6th | Loughton, East of England | Good |
| 21 | Queens' School Period 202425 | 67.8% | Academy · Day · 6th | Bushey, East of England | — |
| 22 | Roundwood Park School Period 202425 | 67.0% | Academy · Day · 6th | Harpenden, East of England | Outstanding |
| 23 | The Broxbourne School Period 202425 | 66.8% | Academy · Day · 6th | Broxbourne, East of England | Outstanding |
| 24 | Wymondham College Period 202425 | 66.8% | Academy · Boarding · 6th | Wymondham, East of England | Outstanding |
| 25 | Coleridge Community College Period 202425 | 66.4% | Academy · Day | Cambridge, East of England | — |