| 1 | Bourne Grammar School Period 202425 | 92.1% | Grammar · Day · 6th | Bourne, East Midlands | Good |
| 2 | Caistor Grammar School Period 202425 | 89.4% | Grammar · Day · 6th | Market Rasen, East Midlands | Good |
| 3 | Queen Elizabeth's Grammar School, Horncastle Period 202425 | 89.4% | Grammar · Day · 6th | Horncastle, East Midlands | Good |
| 4 | King Edward VI Grammar School Period 202425 | 81.2% | Grammar · Day · 6th | Louth, East Midlands | Good |
| 5 | The West Bridgford School Period 202425 | 80.7% | Academy · Day · 6th | Nottingham, East Midlands | Outstanding |
| 6 | The Queen Elizabeth's High School, Gainsborough Period 202425 | 79.7% | Grammar · Day · 6th | Gainsborough, East Midlands | Good |
| 7 | Rushcliffe Spencer Academy Period 202425 | 73.7% | Academy · Day · 6th | Nottingham, East Midlands | — |
| 8 | St Mary's Catholic High School, A Catholic Voluntary Academy Period 202425 | 73.3% | Academy · Day · 6th | Chesterfield, East Midlands | Outstanding |
| 9 | Queen Elizabeth's Grammar Alford - A Selective Academy Period 202425 | 72.2% | Grammar · Day · 6th | Alford, East Midlands | Good |
| 10 | The Market Bosworth School Period 202425 | 72.1% | Academy · Day | Nuneaton, East Midlands | Outstanding |
| 11 | Manor High School Period 202425 | 71.6% | Academy · Day | Leicester, East Midlands | — |
| 12 | The Ecclesbourne School Period 202425 | 71.0% | Academy · Day · 6th | Belper, East Midlands | Good |
| 13 | Carlton le Willows Academy Period 202425 | 69.9% | Academy · Day · 6th | Gedling, East Midlands | Inadequate |
| 14 | Toot Hill School Period 202425 | 67.5% | Academy · Day · 6th | Nottingham, East Midlands | Good |
| 15 | Bishop Stopford School Period 202425 | 66.0% | Academy · Day · 6th | Kettering, East Midlands | — |
| 16 | Welland Park Academy Period 202425 | 65.7% | Academy · Day | Market Harborough, East Midlands | — |
| 17 | Gartree High School Period 202425 | 65.1% | Academy · Day | Leicester, East Midlands | — |
| 18 | Landau Forte College Period 202425 | 65.1% | Academy · Day · 6th | Derby, East Midlands | Outstanding |
| 19 | The Becket School Period 202425 | 64.7% | Academy · Day · 6th | West Bridgford, East Midlands | Good |
| 20 | Beauchamp College Period 202425 | 63.3% | Academy · Day · 6th | Leicester, East Midlands | Good |
| 21 | Fernwood School Period 202425 | 63.0% | Academy · Day | Nottingham, East Midlands | Outstanding |
| 22 | Saint Martin's Catholic Voluntary Academy Period 202425 | 62.6% | Academy · Day | Nuneaton, East Midlands | — |
| 23 | The Robert Smyth Academy Period 202425 | 62.6% | Academy · Day · 6th | Market Harborough, East Midlands | — |
| 24 | Skegness Grammar School Period 202425 | 62.0% | Grammar · Day · 6th | Skegness, East Midlands | Good |
| 25 | John Flamsteed Community School Period 202425 | 60.9% | Academy · Day | Ripley, East Midlands | — |