| 1 | Caistor Grammar School Period 202425 | 69.8 | Grammar · Day · 6th | Market Rasen, East Midlands | Good |
| 2 | Bourne Grammar School Period 202425 | 68.6 | Grammar · Day · 6th | Bourne, East Midlands | Good |
| 3 | Queen Elizabeth's Grammar School, Horncastle Period 202425 | 66.2 | Grammar · Day · 6th | Horncastle, East Midlands | Good |
| 4 | The West Bridgford School Period 202425 | 62.9 | Academy · Day · 6th | Nottingham, East Midlands | Outstanding |
| 5 | The Queen Elizabeth's High School, Gainsborough Period 202425 | 62.5 | Grammar · Day · 6th | Gainsborough, East Midlands | Good |
| 6 | King Edward VI Grammar School Period 202425 | 61.3 | Grammar · Day · 6th | Louth, East Midlands | Good |
| 7 | Queen Elizabeth's Grammar Alford - A Selective Academy Period 202425 | 60.5 | Grammar · Day · 6th | Alford, East Midlands | Good |
| 8 | The Market Bosworth School Period 202425 | 59.5 | Academy · Day | Nuneaton, East Midlands | Outstanding |
| 9 | St Mary's Catholic High School, A Catholic Voluntary Academy Period 202425 | 59.4 | Academy · Day · 6th | Chesterfield, East Midlands | Outstanding |
| 10 | Manor High School Period 202425 | 58.9 | Academy · Day | Leicester, East Midlands | — |
| 11 | Bishop Stopford School Period 202425 | 58.7 | Academy · Day · 6th | Kettering, East Midlands | — |
| 12 | The Ecclesbourne School Period 202425 | 58.3 | Academy · Day · 6th | Belper, East Midlands | Good |
| 13 | Rushcliffe Spencer Academy Period 202425 | 58.1 | Academy · Day · 6th | Nottingham, East Midlands | — |
| 14 | The Becket School Period 202425 | 57.3 | Academy · Day · 6th | West Bridgford, East Midlands | Good |
| 15 | Toot Hill School Period 202425 | 55.9 | Academy · Day · 6th | Nottingham, East Midlands | Good |
| 16 | Beauchamp College Period 202425 | 55.9 | Academy · Day · 6th | Leicester, East Midlands | Good |
| 17 | Landau Forte College Period 202425 | 55.4 | Academy · Day · 6th | Derby, East Midlands | Outstanding |
| 18 | The Trinity Catholic School A Voluntary Academy Period 202425 | 55.3 | Academy · Day · 6th | Nottingham, East Midlands | — |
| 19 | De Lisle College Loughborough Leicestershire Period 202425 | 55.1 | Academy · Day · 6th | Loughborough, East Midlands | — |
| 20 | Carlton le Willows Academy Period 202425 | 55.1 | Academy · Day · 6th | Gedling, East Midlands | Inadequate |
| 21 | St Paul's Catholic School, a Voluntary Academy Period 202425 | 54.5 | Academy · Day · 6th | Leicester, East Midlands | — |
| 22 | Saint Martin's Catholic Voluntary Academy Period 202425 | 54.3 | Academy · Day | Nuneaton, East Midlands | — |
| 23 | Gartree High School Period 202425 | 54.0 | Academy · Day | Leicester, East Midlands | — |
| 24 | English Martyrs' Catholic School, A Voluntary Academy Period 202425 | 54.0 | Academy · Day · 6th | Leicester, East Midlands | — |
| 25 | The Priory Academy LSST Period 202425 | 53.9 | Academy · Day · 6th | Lincoln, East Midlands | Good |