| 1 | Magdalen College School Period 202425 | 71.8% | Academy · Day · 6th | Brackley, East Midlands | — |
| 2 | Pate's Grammar School Period 202425 | 71.3% | Grammar · Day · 6th | Cheltenham, South West | Outstanding |
| 3 | The Latymer School Period 202425 | 63.2% | Grammar · Day · 6th | London, London | Good |
| 4 | Brampton Manor Academy Period 202425 | 59.8% | Academy · Day · 6th | London, London | — |
| 5 | The Blue Coat School Period 202425 | 58.2% | Grammar · Day · 6th | Liverpool, North West | Good |
| 6 | Colyton Grammar School Period 202425 | 58.2% | Grammar · Day · 6th | Colyton, South West | Outstanding |
| 7 | Trinity School Period 202425 | 57.6% | Free School · Day · 6th | Sevenoaks, South East | — |
| 8 | Crofton Academy Period 202425 | 55.8% | Academy · Day | Wakefield, Yorkshire and the Humber | Good |
| 9 | Michaela Community School Period 202425 | 54.1% | Free School · Day · 6th | London, London | — |
| 10 | Langley Grammar School Period 202425 | 54.1% | Grammar · Day · 6th | Langley, South East | Outstanding |
| 11 | Royal Latin School Period 202425 | 52.1% | Grammar · Day · 6th | Buckingham, South East | Good |
| 12 | Dame Alice Owen's School Period 202425 | 50.9% | Academy · Day · 6th | Potters Bar, East of England | Outstanding |
| 13 | The JCB Academy Period 202425 | 50.0% | Free School · Day · 6th | Rocester, West Midlands | Good |
| 14 | Ralph Thoresby School Period 202425 | 50.0% | State · Day · 6th | Leeds, Yorkshire and the Humber | — |
| 15 | The Community College, Bishop's Castle Period 202425 | 49.5% | State · Day | Bishops Castle, West Midlands | — |
| 16 | The Lakes School Period 202425 | 45.5% | State · Day · 6th | Windermere, North West | Good |
| 17 | Sir William Borlase's Grammar School Period 202425 | 44.4% | Grammar · Day · 6th | Marlow, South East | Outstanding |
| 18 | Holmleigh Park High School Period 202425 | 43.8% | Academy · Day · 6th | Gloucester, South West | Good |
| 19 | Chesham Grammar School Period 202425 | 43.3% | Grammar · Day · 6th | Chesham, South East | — |
| 20 | West London Free School Period 202425 | 42.7% | Free School · Day · 6th | London, London | Good |
| 21 | Camborne Science and International Academy Period 202425 | 41.4% | Academy · Day · 6th | Camborne, South West | Good |
| 22 | Christ's Church of England Comprehensive Secondary School Period 202425 | 41.1% | State · Day · 6th | Richmond, London | — |
| 23 | King Edward VI Five Ways School Period 202425 | 40.9% | Grammar · Day · 6th | Birmingham, West Midlands | Good |
| 24 | Upton Court Grammar School Period 202425 | 40.8% | Grammar · Day · 6th | Slough, South East | Outstanding |
| 25 | The Regis School Period 202425 | 40.7% | Academy · Day · 6th | West Sussex, South East | — |