| 101 | King Edward VI King's Norton School for Boys Period 202425 | 56.1% | Academy · Day | Birmingham, West Midlands | Good |
| 102 | Verulam School Period 202425 | 55.3% | Academy · Day · 6th | St Albans, East of England | — |
| 103 | Harris Boys' Academy East Dulwich Period 202425 | 55.1% | Academy · Day · 6th | London, London | Outstanding |
| 104 | St Margaret's Church of England Academy Period 202425 | 54.4% | Academy · Day · 6th | Liverpool, North West | Good |
| 105 | Rokeby School Period 202425 | 54.3% | Academy · Day | London, London | — |
| 106 | Enfield Grammar School Period 202425 | 53.8% | Academy · Day · 6th | Enfield, London | — |
| 107 | Challney High School for Boys Period 202425 | 53.7% | Academy · Day | Luton, East of England | Outstanding |
| 108 | The Boston Grammar School Period 202425 | 53.6% | Grammar · Day · 6th | Boston, East Midlands | Good |
| 109 | Desborough College Period 202425 | 53.5% | Academy · Day · 6th | Maidenhead, South East | — |
| 110 | St Columba's Catholic Boys' School Period 202425 | 53.2% | Academy · Day | Bexleyheath, London | — |
| 111 | William Ellis School Period 202425 | 52.6% | State · Day · 6th | London, London | — |
| 112 | The Windsor Boys' School Period 202425 | 52.6% | Academy · Day · 6th | Windsor, South East | — |
| 113 | Norlington School and 6th Form Period 202425 | 52.0% | Academy · Day · 6th | London, London | — |
| 114 | Hutton Church of England Grammar School Period 202425 | 51.7% | State · Day · 6th | Preston, North West | — |
| 115 | St Cuthbert's High School Period 202425 | 51.5% | Academy · Day · 6th | Newcastle-upon-Tyne, North East | Good |
| 116 | Southborough High School Period 202425 | 51.2% | Academy · Day · 6th | Surbiton, London | Good |
| 117 | St Birinus School Period 202425 | 50.9% | Academy · Day · 6th | Didcot, South East | — |
| 118 | Westminster City School Period 202425 | 50.0% | Academy · Day · 6th | London, London | — |
| 119 | Audenshaw School Period 202425 | 49.8% | Academy · Day | Manchester, North West | Good |
| 120 | Sandbach School Period 202425 | 49.6% | Free School · Day · 6th | Sandbach, North West | — |
| 121 | Mulberry Stepney Green Mathematics and Computing College Period 202425 | 48.9% | Academy · Day · 6th | London, London | — |
| 122 | Beverley Grammar School Period 202425 | 48.6% | Academy · Day · 6th | Beverley, Yorkshire and the Humber | Outstanding |
| 123 | St Bonaventure's RC School Period 202425 | 46.9% | State · Day · 6th | London, London | Outstanding |
| 124 | Woolwich Polytechnic School Period 202425 | 46.6% | Academy · Day · 6th | London, London | — |
| 125 | Burnage Academy for Boys Period 202425 | 46.3% | Academy · Day | Manchester, North West | — |