| 51 | Ermysted's Grammar School Period 202425 | 86.7% | Grammar · Day · 6th | Skipton, Yorkshire and the Humber | Good |
| 52 | The Harvey Grammar School Period 202425 | 85.5% | Grammar · Day · 6th | Folkestone, South East | — |
| 53 | Holcombe Grammar School Period 202425 | 84.7% | Grammar · Day · 6th | Chatham, South East | — |
| 54 | Watford Grammar School for Boys Period 202425 | 83.3% | Academy · Day · 6th | Watford, East of England | Outstanding |
| 55 | Borden Grammar School Period 202425 | 83.1% | Grammar · Day · 6th | Sittingbourne, South East | — |
| 56 | Tauheedul Islam Boys' High School Period 202425 | 80.9% | Free School · Day · 6th | Blackburn, North West | Outstanding |
| 57 | Gunnersbury Catholic School Period 202425 | 80.7% | State · Day · 6th | Brentford, London | Outstanding |
| 58 | The Cardinal Vaughan Memorial RC School Period 202425 | 80.2% | Academy · Day · 6th | London, London | Outstanding |
| 59 | Finchley Catholic High School Period 202425 | 78.6% | State · Day · 6th | London, London | — |
| 60 | Carre's Grammar School Period 202425 | 78.3% | Grammar · Day · 6th | Sleaford, East Midlands | Good |
| 61 | The London Oratory School Period 202425 | 77.6% | Academy · Day · 6th | London, London | Outstanding |
| 62 | Eden Boys' School, Birmingham Period 202425 | 76.2% | Free School · Day | Birmingham, West Midlands | — |
| 63 | St Anselm's College Period 202425 | 75.5% | Grammar · Day · 6th | Prenton, North West | — |
| 64 | Spalding Grammar School Period 202425 | 75.2% | Grammar · Day · 6th | Spalding, East Midlands | Good |
| 65 | Eden Boys' Leadership Academy, Birmingham East Period 202425 | 74.8% | Free School · Day | Birmingham, West Midlands | Outstanding |
| 66 | Richard Challoner School Period 202425 | 74.7% | Academy · Day · 6th | New Malden, London | Outstanding |
| 67 | Hasmonean High School for Boys Period 202425 | 73.9% | Academy · Day · 6th | London, London | Good |
| 68 | Winton Academy Period 202425 | 73.4% | Academy · Day | Bournemouth, South West | — |
| 69 | The St Thomas the Apostle College Period 202425 | 72.0% | State · Day · 6th | London, London | — |
| 70 | Northampton School for Boys Period 202425 | 71.6% | Academy · Day · 6th | Northampton, East Midlands | — |
| 71 | The Fulham Boys School Period 202425 | 70.0% | Free School · Day · 6th | London, London | Good |
| 72 | The Bishop's Stortford High School Period 202425 | 69.2% | State · Day · 6th | Bishop's Stortford, East of England | — |
| 73 | Central Foundation Boys' School Period 202425 | 68.8% | State · Day · 6th | London, London | — |
| 74 | Wimbledon College Period 202425 | 68.6% | State · Day · 6th | London, London | — |
| 75 | Eden Boys' School, Preston Period 202425 | 67.7% | Free School · Day | Preston, North West | — |