| 101 | Westminster City School Period 202425 | 4.51 | Academy · Day · 6th | London, London | — |
| 102 | Mulberry Stepney Green Mathematics and Computing College Period 202425 | 4.51 | Academy · Day · 6th | London, London | — |
| 103 | Madani Boys School Period 202425 | 4.48 | State · Day | Leicester, East Midlands | — |
| 104 | Eden Boys' Leadership Academy, Bradford Period 202425 | 4.48 | Free School · Day · 6th | Bradford, Yorkshire and the Humber | Outstanding |
| 105 | St Cuthbert's High School Period 202425 | 4.45 | Academy · Day · 6th | Newcastle-upon-Tyne, North East | Good |
| 106 | St Birinus School Period 202425 | 4.44 | Academy · Day · 6th | Didcot, South East | — |
| 107 | St Columba's Catholic Boys' School Period 202425 | 4.42 | Academy · Day | Bexleyheath, London | — |
| 108 | Bullers Wood School for Boys Period 202425 | 4.42 | Free School · Day | Bromley, London | Good |
| 109 | Avonbourne Boys' Academy Period 202425 | 4.38 | Academy · Day | Bournemouth, South West | Outstanding |
| 110 | Hutton Church of England Grammar School Period 202425 | 4.37 | State · Day · 6th | Preston, North West | — |
| 111 | Ernest Bevin Academy Period 202425 | 4.34 | Academy · Day · 6th | London, London | Good |
| 112 | King Edward VI King's Norton School for Boys Period 202425 | 4.34 | Academy · Day | Birmingham, West Midlands | Good |
| 113 | Norlington School and 6th Form Period 202425 | 4.30 | Academy · Day · 6th | London, London | — |
| 114 | The Windsor Boys' School Period 202425 | 4.30 | Academy · Day · 6th | Windsor, South East | — |
| 115 | St Thomas More High School Period 202425 | 4.28 | Academy · Day · 6th | Westcliff-on-Sea, East of England | — |
| 116 | Enfield Grammar School Period 202425 | 4.26 | Academy · Day · 6th | Enfield, London | — |
| 117 | Challney High School for Boys Period 202425 | 4.21 | Academy · Day | Luton, East of England | Outstanding |
| 118 | The Green School for Boys Period 202425 | 4.18 | Free School · Day · 6th | Isleworth, London | Good |
| 119 | Wheelers Lane Technology College Period 202425 | 4.18 | State · Day | Birmingham, West Midlands | — |
| 120 | Southborough High School Period 202425 | 4.15 | Academy · Day · 6th | Surbiton, London | Good |
| 121 | Carshalton Boys Sports College Period 202425 | 4.13 | Academy · Day · 6th | Carshalton, London | Good |
| 122 | Leigh Academy Tonbridge Period 202425 | 4.12 | Academy · Day · 6th | Tonbridge, South East | Good |
| 123 | St Joseph's College Period 202425 | 4.08 | Academy · Day · 6th | London, London | Good |
| 124 | Desborough College Period 202425 | 4.06 | Academy · Day · 6th | Maidenhead, South East | — |
| 125 | Upper Batley High School Period 202425 | 4.05 | Academy · Day | Batley, Yorkshire and the Humber | — |