| 101 | Hitchin Boys' School | 50.8 composite | Academy · Day · 6th | Hitchin, East of England | — 2021-09-22 |
| 102 | Central Foundation Boys' School | 50.8 composite | State · Day · 6th | London, London | — 2025-03-11 |
| 103 | Coombe Boys' School | 50.0 composite | Academy · Day · 6th | New Malden, London | — 2023-09-13 |
| 104 | The Green School for Boys | 49.9 compositeOfsted17.5 Att817.4 EM5+15.0 | Free School · Day · 6th | Isleworth, London | Good 2020-02-25×0.7 |
| 105 | The John Fisher School | 49.5 composite | State · Day · 6th | Purley, London | — 2023-06-21 |
| 106 | Kings Heath Secondary School | 49.3 compositeOfsted21.2 Att814.8 EM5+13.2 | State · Day | Birmingham, West Midlands | Good 2023-03-08×0.85 |
| 107 | St Ignatius College | 48.3 composite | State · Day · 6th | Enfield, London | — 2025-02-11 |
| 108 | Eden Boys' School, Preston | 48.0 composite | Free School · Day | Preston, North West | — 2024-05-16 |
| 109 | St Thomas More High School | 47.5 composite | Academy · Day · 6th | Westcliff-on-Sea, East of England | — 2024-03-07 |
| 110 | SGS Berkeley Green UTC | 47.3 compositeOfsted21.2 Att815.3 EM5+10.8 | Free School · Day · 6th | Berkeley, South West | Good 2022-02-15×0.85 |
| 111 | The Royal Liberty School | 47.3 composite | Academy · Day | Romford, London | — 2024-02-08 |
| 112 | Leigh Academy Tonbridge | 47.3 compositeOfsted21.2 Att816.0 EM5+10.0 | Academy · Day · 6th | Tonbridge, South East | Good 2022-12-06×0.85 |
| 113 | Wellacre Technology Academy | 47.2 compositeOfsted16.7 Att817.0 EM5+13.5 | Academy · Day | Manchester, North West | Requires Improvement 2023-10-17 |
| 114 | The Campion School | 47.2 composite | Academy · Day · 6th | Hornchurch, London | — 2021-11-25 |
| 115 | Langley Park School for Boys | 46.9 composite | Academy · Day · 6th | Beckenham, London | — 2024-11-27 |
| 116 | St Aidan's Catholic Academy | 46.6 composite | Academy · Day · 6th | Sunderland, North East | — 2025-02-18 |
| 117 | Madani Boys School | 46.6 composite | State · Day | Leicester, East Midlands | — 2025-05-08 |
| 118 | Salvatorian Roman Catholic College | 46.3 composite | Academy · Day · 6th | Harrow, London | — 2022-02-23 |
| 119 | St Joseph's College | 46.1 compositeOfsted17.5 Att816.9 EM5+11.7 | Academy · Day · 6th | London, London | Good 2020-02-25×0.7 |
| 120 | Eden Boys' School, Bolton | 45.8 composite | Free School · Day | Bolton, North West | — 2023-07-04 |
| 121 | Birkdale High School | 44.9 composite | Academy · Day | Southport, North West | — 2022-06-16 |
| 122 | Verulam School | 44.3 composite | Academy · Day · 6th | St Albans, East of England | — 2024-05-22 |
| 123 | Marylebone Boys' School | 44.1 composite | Free School · Day · 6th | London, London | — 2022-11-16 |
| 124 | Northfleet Technology College | 43.7 compositeOfsted21.2 Att813.2 EM5+9.2 | State · Day · 6th | Gravesend, South East | Good 2022-09-21×0.85 |
| 125 | Hurstmere School | 43.6 compositeOfsted14.2 Att815.6 EM5+13.8 | Academy · Day | Sidcup, London | Requires Improvement 2022-09-27×0.85 |