| 76 | Beths Grammar School | 41.9 composite | Grammar · Day · 6th | Bexley, London | Good 2022-05-04×0.85 |
| 77 | Southborough High School | 41.3 composite | Academy · Day · 6th | Surbiton, London | Good 2023-02-02×0.85 |
| 78 | Turves Green Boys' School | 41.3 composite | Academy · Day | Birmingham, West Midlands | Good 2024-03-19 |
| 79 | King Edward VI King's Norton School for Boys | 41.3 composite | Academy · Day | Birmingham, West Midlands | Good 2023-07-03 |
| 80 | The Forest School | 39.9 composite | Academy · Day · 6th | Wokingham, South East | Good 2021-06-29×0.85 |
| 81 | St Francis Xavier's Catholic Academy | 37.9 composite | Academy · Day · 6th | Liverpool, North West | Requires Improvement 2021-10-12×0.85 |
| 82 | Desborough College | 37.6 composite | Academy · Day · 6th | Maidenhead, South East | — 2024-05-17 |
| 83 | Silverstone UTC | 36.8 composite | Free School · Day · 6th | Towcester, East Midlands | Requires Improvement 2023-11-28 |
| 84 | The Mosslands School | 36.7 composite | State · Day · 6th | Wallasey, North West | Requires Improvement 2024-02-28 |
| 85 | Norlington School and 6th Form | 36.5 composite | Academy · Day · 6th | London, London | — 2023-11-30 |
| 86 | Poole Grammar School | 36.4 composite | Grammar · Day · 6th | Poole, South West | — 2025-05-13 |
| 87 | Hitchin Boys' School | 35.9 composite | Academy · Day · 6th | Hitchin, East of England | — 2021-09-22 |
| 88 | The St Thomas the Apostle College | 35.5 composite | State · Day · 6th | London, London | — 2024-11-06 |
| 89 | The Green School for Boys | 35.1 composite | Free School · Day · 6th | Isleworth, London | Good 2020-02-25×0.7 |
| 90 | Kings Heath Secondary School | 35.1 composite | State · Day | Birmingham, West Midlands | Good 2023-03-08×0.85 |
| 91 | Lordswood Boys' School | 35.1 composite | Academy · Day | Birmingham, West Midlands | Good 2022-02-15×0.85 |
| 92 | Bullers Wood School for Boys | 35.1 composite | Free School · Day | Bromley, London | Good 2023-02-07×0.85 |
| 93 | Eden Boys' Leadership Academy, Manchester | 35.1 composite | Free School · Day · 6th | Manchester, North West | Good 2021-11-23×0.85 |
| 94 | Audenshaw School | 35.1 composite | Academy · Day | Manchester, North West | Good 2023-03-13×0.85 |
| 95 | Rutlish School | 34.8 composite | State · Day · 6th | London, London | — 2024-09-24 |
| 96 | Manchester Mesivta School | 34.8 composite | State · Day · 6th | Prestwich, North West | Requires Improvement 2024-01-30 |
| 97 | UTC Swindon | 34.8 composite | Free School · Day · 6th | Swindon, South West | Requires Improvement 2024-05-08 |
| 98 | St Anselm's College | 34.5 composite | Grammar · Day · 6th | Prenton, North West | — 2025-03-19 |
| 99 | Wimbledon College | 34.0 composite | State · Day · 6th | London, London | — 2023-03-22 |
| 100 | Newman Catholic College | 33.8 composite | State · Day · 6th | London, London | — 2022-05-05 |