| 51 | King Edward VI Aston School Period 202425 | 26.0% | Grammar · Day · 6th | Birmingham, West Midlands | Outstanding |
| 52 | Devonport High School for Boys Period 202425 | 25.0% | Grammar · Day · 6th | Plymouth, South West | Good |
| 53 | Calday Grange Grammar School Period 202425 | 24.8% | Grammar · Day · 6th | Wirral, North West | — |
| 54 | Gunnersbury Catholic School Period 202425 | 24.6% | State · Day · 6th | Brentford, London | Outstanding |
| 55 | St Joseph's College Period 202425 | 23.8% | Academy · Day · 6th | London, London | Good |
| 56 | Simon Langton Grammar School for Boys Period 202425 | 23.4% | Grammar · Day · 6th | Canterbury, South East | — |
| 57 | Maidstone Grammar School Period 202425 | 22.7% | Grammar · Day · 6th | Maidstone, South East | — |
| 58 | St Anselm's College Period 202425 | 21.8% | Grammar · Day · 6th | Prenton, North West | — |
| 59 | Norlington School and 6th Form Period 202425 | 21.7% | Academy · Day · 6th | London, London | — |
| 60 | SGS Berkeley Green UTC Period 202425 | 21.4% | Free School · Day · 6th | Berkeley, South West | Good |
| 61 | Beechen Cliff School Period 202425 | 21.1% | Academy · Boarding · 6th | Bath, South West | Good |
| 62 | Harris Boys' Academy East Dulwich Period 202425 | 21.1% | Academy · Day · 6th | London, London | Outstanding |
| 63 | Oakwood Park Grammar School Period 202425 | 20.0% | Grammar · Day · 6th | Maidstone, South East | — |
| 64 | Tunbridge Wells Grammar School for Boys Period 202425 | 20.0% | Grammar · Day · 6th | Tunbridge Wells, South East | — |
| 65 | Carre's Grammar School Period 202425 | 19.2% | Grammar · Day · 6th | Sleaford, East Midlands | Good |
| 66 | University Technical College Leeds Period 202425 | 18.2% | Free School · Day · 6th | Leeds, Yorkshire and the Humber | Good |
| 67 | The Bishop's Stortford High School Period 202425 | 18.0% | State · Day · 6th | Bishop's Stortford, East of England | — |
| 68 | Marling School Period 202425 | 17.6% | Grammar · Day · 6th | Stroud, South West | — |
| 69 | Beverley Grammar School Period 202425 | 17.1% | Academy · Day · 6th | Beverley, Yorkshire and the Humber | Outstanding |
| 70 | Hutton Church of England Grammar School Period 202425 | 16.9% | State · Day · 6th | Preston, North West | — |
| 71 | The Windsor Boys' School Period 202425 | 16.5% | Academy · Day · 6th | Windsor, South East | — |
| 72 | St Aidan's Catholic Academy Period 202425 | 16.2% | Academy · Day · 6th | Sunderland, North East | — |
| 73 | St Cuthbert's High School Period 202425 | 15.9% | Academy · Day · 6th | Newcastle-upon-Tyne, North East | Good |
| 74 | Spalding Grammar School Period 202425 | 15.7% | Grammar · Day · 6th | Spalding, East Midlands | Good |
| 75 | Verulam School Period 202425 | 15.4% | Academy · Day · 6th | St Albans, East of England | — |