| 26 | Bishop Wordsworth's Church of England Grammar School Period 202425 | 32.8% | Grammar · Day · 6th | Salisbury, South West | Outstanding |
| 27 | Sir Thomas Rich's School Period 202425 | 32.5% | Grammar · Day · 6th | Gloucester, South West | Good |
| 28 | Haberdashers' Adams Period 202425 | 32.3% | Grammar · Boarding · 6th | Newport, West Midlands | Good |
| 29 | Poole Grammar School Period 202425 | 32.1% | Grammar · Day · 6th | Poole, South West | — |
| 30 | John Hampden Grammar School Period 202425 | 31.4% | Grammar · Day · 6th | High Wycombe, South East | Outstanding |
| 31 | The Cardinal Vaughan Memorial RC School Period 202425 | 31.3% | Academy · Day · 6th | London, London | Outstanding |
| 32 | King Edward VI Handsworth Grammar School for Boys Period 202425 | 31.3% | Grammar · Day · 6th | Birmingham, West Midlands | Good |
| 33 | The Skinners' School Period 202425 | 31.0% | Grammar · Day · 6th | Tunbridge Wells, South East | Good |
| 34 | West Derby School Period 202425 | 30.4% | Academy · Day · 6th | Liverpool, North West | Good |
| 35 | The St Thomas the Apostle College Period 202425 | 29.9% | State · Day · 6th | London, London | — |
| 36 | Rutlish School Period 202425 | 29.7% | State · Day · 6th | London, London | — |
| 37 | The London Oratory School Period 202425 | 29.0% | Academy · Day · 6th | London, London | Outstanding |
| 38 | Ermysted's Grammar School Period 202425 | 28.6% | Grammar · Day · 6th | Skipton, Yorkshire and the Humber | Good |
| 39 | Lawrence Sheriff School Period 202425 | 28.5% | Grammar · Day · 6th | Rugby, West Midlands | Outstanding |
| 40 | Torquay Boys' Grammar School Period 202425 | 28.3% | Grammar · Day · 6th | Torquay, South West | Good |
| 41 | Bournemouth School Period 202425 | 28.3% | Grammar · Day · 6th | Bournemouth, South West | Outstanding |
| 42 | Sir Joseph Williamson's Mathematical School Period 202425 | 27.6% | Grammar · Day · 6th | Rochester, South East | Outstanding |
| 43 | Gravesend Grammar School Period 202425 | 26.9% | Grammar · Day · 6th | Gravesend, South East | — |
| 44 | Tauheedul Islam Boys' High School Period 202425 | 26.9% | Free School · Day · 6th | Blackburn, North West | Outstanding |
| 45 | Carshalton Boys Sports College Period 202425 | 26.8% | Academy · Day · 6th | Carshalton, London | Good |
| 46 | Southend High School for Boys Period 202425 | 26.7% | Grammar · Day · 6th | Southend-on-Sea, East of England | Outstanding |
| 47 | Northampton School for Boys Period 202425 | 26.7% | Academy · Day · 6th | Northampton, East Midlands | — |
| 48 | Wimbledon College Period 202425 | 26.6% | State · Day · 6th | London, London | — |
| 49 | Wirral Grammar School for Boys Period 202425 | 26.5% | Grammar · Day · 6th | Wirral, North West | Good |
| 50 | Watford Grammar School for Boys Period 202425 | 26.5% | Academy · Day · 6th | Watford, East of England | Outstanding |