| 1776 | The Saint John Henry Newman Catholic School | 1,605 pupils | Academy · Day · 6th | Stevenage, East of England | — |
| 1777 | Ashton-on-Mersey School | 1,600 pupils | Academy · Day · 6th | Sale, North West | — |
| 1778 | Oakwood School | 1,600 pupils | State · Day | Horley, South East | — |
| 1779 | Sackville School | 1,599 pupils | State · Day · 6th | East Grinstead, South East | — |
| 1780 | Christopher Whitehead Language College | 1,596 pupils | Academy · Day · 6th | Worcester, West Midlands | — |
| 1781 | Valley Park School | 1,595 pupils | Academy · Day · 6th | Maidstone, South East | — |
| 1782 | Ravens Wood School | 1,592 pupils | Academy · Day · 6th | Bromley, London | — |
| 1783 | Woolwich Polytechnic School | 1,592 pupils | Academy · Day · 6th | London, London | — |
| 1784 | Lytchett Minster School | 1,590 pupils | State · Day · 6th | Poole, South West | — |
| 1785 | The Hazeley Academy | 1,590 pupils | Academy · Day · 6th | Milton Keynes, South East | — |
| 1786 | Brentside High School | 1,589 pupils | State · Day · 6th | London, London | — |
| 1787 | St Robert of Newminster Catholic School and Sixth Form College, Washington | 1,588 pupils | Academy · Day · 6th | Washington, North East | — |
| 1788 | Aldridge School - A Science College | 1,585 pupils | Academy · Day · 6th | Walsall, West Midlands | — |
| 1789 | Tring School | 1,584 pupils | Academy · Day · 6th | Tring, East of England | — |
| 1790 | Paignton Academy | 1,582 pupils | Academy · Day | Paignton, South West | — |
| 1791 | Elthorne Park High School | 1,580 pupils | State · Day · 6th | London, London | — |
| 1792 | Thornleigh Salesian College | 1,576 pupils | State · Day · 6th | Bolton, North West | — |
| 1793 | Minsthorpe Community College | 1,575 pupils | Academy · Day · 6th | Pontefract, Yorkshire and the Humber | — |
| 1794 | The Gilberd School | 1,574 pupils | Academy · Day | Colchester, East of England | — |
| 1795 | Imberhorne School | 1,573 pupils | State · Day · 6th | East Grinstead, South East | — |
| 1796 | Bourne Academy | 1,571 pupils | Academy · Day · 6th | Bourne, East Midlands | — |
| 1797 | Plantsbrook School | 1,570 pupils | Academy · Day · 6th | Sutton Coldfield, West Midlands | — |
| 1798 | North Chadderton School | 1,569 pupils | Academy · Day · 6th | Oldham, North West | — |
| 1799 | Highcliffe School | 1,565 pupils | Academy · Day · 6th | Christchurch, South West | — |
| 1800 | Soar Valley College | 1,564 pupils | Academy · Day | Leicester, East Midlands | — |