| 1701 | Horsforth School | 1,773 pupils | Academy · Day · 6th | Leeds, Yorkshire and the Humber | — |
| 1702 | Norton Hill Academy | 1,765 pupils | Academy · Day · 6th | Radstock, South West | — |
| 1703 | Tapton School & Sixth Form | 1,763 pupils | Academy · Day · 6th | Sheffield, Yorkshire and the Humber | — |
| 1704 | Windsor High School and Sixth Form | 1,760 pupils | Academy · Day · 6th | Halesowen, West Midlands | — |
| 1705 | Upton-by-Chester High School | 1,752 pupils | State · Day · 6th | Chester, North West | — |
| 1706 | Canon Slade School | 1,747 pupils | Academy · Day · 6th | Bolton, North West | — |
| 1707 | Westlands School | 1,746 pupils | Academy · Day · 6th | Sittingbourne, South East | — |
| 1708 | Myton School | 1,743 pupils | Academy · Day · 6th | Warwick, West Midlands | — |
| 1709 | Whitmore High School | 1,739 pupils | State · Day · 6th | Harrow, London | — |
| 1710 | Outwood Academy Portland | 1,726 pupils | Academy · Day · 6th | Worksop, East Midlands | — |
| 1711 | Neston High School | 1,724 pupils | Academy · Day · 6th | Neston, North West | — |
| 1712 | Whickham School | 1,721 pupils | Academy · Day · 6th | Newcastle-upon-Tyne, North East | — |
| 1713 | Collingwood College | 1,714 pupils | Academy · Day · 6th | Camberley, South East | — |
| 1714 | Kenton School | 1,713 pupils | Academy · Day · 6th | Newcastle-upon-Tyne, North East | — |
| 1715 | Northampton School for Boys | 1,713 pupils | Academy · Day · 6th | Northampton, East Midlands | — |
| 1716 | St John's Marlborough | 1,712 pupils | Academy · Day · 6th | Marlborough, South West | — |
| 1717 | St Martin's School Brentwood | 1,711 pupils | Academy · Day · 6th | Brentwood, East of England | — |
| 1718 | Derby Moor Spencer Academy | 1,709 pupils | Academy · Day · 6th | Derby, East Midlands | — |
| 1719 | Northgate High School | 1,709 pupils | State · Day · 6th | Ipswich, East of England | — |
| 1720 | City of Norwich School, An Ormiston Academy | 1,708 pupils | Academy · Day · 6th | Norwich, East of England | — |
| 1721 | Finham Park School | 1,705 pupils | Academy · Day · 6th | Coventry, West Midlands | — |
| 1722 | Tudor Grange Academy, Solihull | 1,705 pupils | Academy · Day · 6th | Solihull, West Midlands | — |
| 1723 | Cheney School | 1,704 pupils | Academy · Day · 6th | Oxford, South East | — |
| 1724 | The Billericay School | 1,702 pupils | Academy · Day · 6th | Billericay, East of England | — |
| 1725 | Allerton High School | 1,697 pupils | State · Day · 6th | Leeds, Yorkshire and the Humber | — |