| 1676 | Stratford Upon Avon School | 1,904 pupils | Academy · Day · 6th | Stratford-upon-Avon, West Midlands | — |
| 1677 | Weald of Kent Grammar School | 1,902 pupils | Grammar · Day · 6th | Tonbridge, South East | — |
| 1678 | St Paul's Catholic School | 1,886 pupils | State · Day · 6th | Milton Keynes, South East | — |
| 1679 | Shenley Brook End School | 1,883 pupils | Academy · Day · 6th | Milton Keynes, South East | — |
| 1680 | Garforth Academy | 1,880 pupils | Academy · Day · 6th | Leeds, Yorkshire and the Humber | — |
| 1681 | Poole High School | 1,875 pupils | Academy · Day · 6th | Poole, South West | — |
| 1682 | Parrs Wood High School | 1,867 pupils | Academy · Day · 6th | Manchester, North West | — |
| 1683 | The Crompton House Church of England Academy | 1,859 pupils | Academy · Day · 6th | Oldham, North West | — |
| 1684 | Clacton County High School | 1,854 pupils | Academy · Day · 6th | Clacton-on-Sea, East of England | — |
| 1685 | Salesian School, Chertsey | 1,849 pupils | Academy · Day · 6th | Chertsey, South East | — |
| 1686 | Cleeve School | 1,848 pupils | Academy · Day · 6th | Cheltenham, South West | — |
| 1687 | Mayfield School | 1,845 pupils | State · Day · 6th | Dagenham, London | — |
| 1688 | Thorpe St Andrew School and Sixth Form | 1,834 pupils | Academy · Day · 6th | Norwich, East of England | — |
| 1689 | Langley Park School for Boys | 1,820 pupils | Academy · Day · 6th | Beckenham, London | — |
| 1690 | Wales High School | 1,815 pupils | Academy · Day · 6th | Sheffield, Yorkshire and the Humber | — |
| 1691 | Wright Robinson College | 1,810 pupils | Academy · Day | Manchester, North West | — |
| 1692 | Brookfield Community School | 1,805 pupils | State · Day | Southampton, South East | — |
| 1693 | Tunbridge Wells Grammar School for Boys | 1,799 pupils | Grammar · Day · 6th | Tunbridge Wells, South East | — |
| 1694 | Winchmore School | 1,788 pupils | State · Day · 6th | London, London | — |
| 1695 | Denbigh School | 1,784 pupils | Academy · Day · 6th | Milton Keynes, South East | — |
| 1696 | Weald School, The | 1,784 pupils | State · Day · 6th | Billingshurst, South East | — |
| 1697 | Rastrick High School | 1,780 pupils | Academy · Day | Brighouse, Yorkshire and the Humber | — |
| 1698 | St Mary Redcliffe and Temple School | 1,778 pupils | State · Day · 6th | Bristol, South West | — |
| 1699 | Woodkirk Academy | 1,775 pupils | Academy · Day · 6th | Wakefield, Yorkshire and the Humber | — |
| 1700 | Featherstone High School | 1,773 pupils | Academy · Day · 6th | Southall, London | — |