| 101 | Parmiter's School | 59.8 compositeOfsted18.0 AAB%4.3 VA9.6 Att813.3 EM5+14.5 | Academy · Day · 6th | Watford, East of England | Outstanding 2024-07-03 |
| 102 | Queen Mary's High School | 59.8 compositeOfsted15.3 AAB%4.6 VA8.0 Att814.7 EM5+17.1 | Grammar · Day · 6th | Walsall, West Midlands | Outstanding 2021-10-12×0.85 |
| 103 | Lancaster Girls' Grammar School | 59.6 compositeOfsted11.5 AAB%6.1 VA10.8 Att814.7 EM5+16.6 | Grammar · Day · 6th | Lancaster, North West | Good 2022-09-21×0.85 |
| 104 | The Hertfordshire & Essex High School and Science College | 59.6 compositeOfsted18.0 AAB%4.1 VA11.2 Att812.7 EM5+13.6 | Academy · Day · 6th | Bishop's Stortford, East of England | Outstanding 2023-11-14 |
| 105 | Watford Grammar School for Boys | 59.3 compositeOfsted15.3 AAB%4.8 VA10.5 Att813.8 EM5+15.0 | Academy · Day · 6th | Watford, East of England | Outstanding 2021-10-13×0.85 |
| 106 | Wirral Grammar School for Girls | 59.3 compositeOfsted15.3 AAB%4.5 VA9.0 Att813.9 EM5+16.6 | Grammar · Day · 6th | Wirral, North West | Outstanding 2022-12-06×0.85 |
| 107 | Queen Elizabeth's Grammar School, Horncastle | 59.2 compositeOfsted13.5 AAB%6.0 VA10.4 Att813.2 EM5+16.1 | Grammar · Day · 6th | Horncastle, East Midlands | Good 2024-06-04 |
| 108 | Holmfirth High School | 59.1 compositeOfsted24.7 Att816.1 EM5+18.4 | State · Day | Holmfirth, Yorkshire and the Humber | Outstanding 2023-06-20 |
| 109 | St Mary's Catholic High School, A Catholic Voluntary Academy | 59.1 compositeOfsted18.0 AAB%4.4 VA11.7 Att811.9 EM5+13.2 | Academy · Day · 6th | Chesterfield, East Midlands | Outstanding 2024-06-26 |
| 110 | Sir John Lawes School | 59.1 compositeOfsted15.3 AAB%5.0 VA12.7 Att812.6 EM5+13.6 | Academy · Day · 6th | Harpenden, East of England | Outstanding 2023-03-28×0.85 |
| 111 | Gunnersbury Catholic School | 58.9 compositeOfsted15.3 AAB%4.4 VA11.9 Att812.7 EM5+14.5 | State · Day · 6th | Brentford, London | Outstanding 2023-01-17×0.85 |
| 112 | Heckmondwike Grammar School | 58.9 compositeOfsted11.5 AAB%4.6 VA8.8 Att816.0 EM5+17.9 | Grammar · Day · 6th | Heckmondwike, Yorkshire and the Humber | Good 2022-04-05×0.85 |
| 113 | The Rochester Grammar School | 58.9 compositeOfsted13.2 VA10.7 Att815.8 EM5+19.2 | Grammar · Day · 6th | Rochester, South East | Good 2023-01-17×0.85 |
| 114 | The Market Bosworth School | 58.8 compositeOfsted24.7 Att816.3 EM5+17.8 | Academy · Day | Nuneaton, East Midlands | Outstanding 2024-06-04 |
| 115 | Mercia School | 58.6 compositeOfsted15.3 AAB%6.9 VA8.0 Att813.6 EM5+14.9 | Free School · Day · 6th | Sheffield, Yorkshire and the Humber | Outstanding 2023-02-08×0.85 |
| 116 | Millbay Academy | 58.5 compositeOfsted11.8 Att86.4 EM5+4.3 RWM14.9 Read11.0 Maths10.2 | Free School · Day | Plymouth, South West | Good 2024-02-27 |
| 117 | Caistor Grammar School | 58.5 compositeOfsted11.5 AAB%5.9 VA11.1 Att814.0 EM5+16.1 | Grammar · Day · 6th | Market Rasen, East Midlands | Good 2022-05-24×0.85 |
| 118 | Wallington High School for Girls | 58.5 compositeAAB%8.6 VA10.6 Att818.6 EM5+20.6 | Grammar · Day · 6th | Wallington, London | — 2025-03-18 |
| 119 | The Holt School | 58.4 compositeOfsted15.3 AAB%6.0 VA9.9 Att812.7 EM5+14.5 | Academy · Day · 6th | Wokingham, South East | Outstanding 2023-03-28×0.85 |
| 120 | Wirral Grammar School for Boys | 58.3 compositeOfsted11.5 AAB%4.8 VA12.6 Att813.1 EM5+16.4 | Grammar · Day · 6th | Wirral, North West | Good 2022-11-08×0.85 |
| 121 | Chesham Grammar School | 58.3 compositeAAB%9.0 VA12.1 Att817.1 EM5+20.1 | Grammar · Day · 6th | Chesham, South East | — 2025-03-04 |
| 122 | The Cardinal Vaughan Memorial RC School | 58.2 compositeOfsted15.3 AAB%5.6 VA9.4 Att813.4 EM5+14.4 | Academy · Day · 6th | London, London | Outstanding 2021-11-16×0.85 |
| 123 | Saint George Catholic Voluntary Aided College Southampton | 58.2 compositeOfsted24.7 Att816.4 EM5+17.1 | State · Day | Southampton, South East | Outstanding 2023-06-27 |
| 124 | Spalding High School | 58.1 compositeOfsted18.0 AAB%2.0 VA11.9 Att812.6 EM5+13.6 | Grammar · Day · 6th | Spalding, East Midlands | Outstanding 2023-11-29 |
| 125 | Bentley Wood High School | 58.0 compositeOfsted18.0 AAB%2.3 VA14.8 Att811.7 EM5+11.2 | Academy · Day · 6th | Stanmore, London | Outstanding 2023-11-14 |