| 1 | Christow Primary School Period 202425 | 116.0 | Academy · Day | Exeter, South West | — |
| 2 | Duloe CofE VA Primary Academy Period 202425 | 114.0 | Academy · Day | Liskeard, South West | — |
| 3 | Trythall Community Primary School Period 202425 | 114.0 | State · Day | Penzance, South West | — |
| 4 | St. Walburga's Catholic Primary School Period 202425 | 113.0 | State · Day | Bournemouth, South West | Good |
| 5 | Lady Seaward's Church of England Primary School Period 202425 | 113.0 | Academy · Day | Exeter, South West | — |
| 6 | Parkend Primary School Period 202425 | 113.0 | State · Day | Lydney, South West | Good |
| 7 | Totnes St John's Church of England Primary School Period 202425 | 113.0 | Academy · Day | Totnes, South West | Good |
| 8 | Braddock CofE Primary School Period 202425 | 113.0 | Academy · Day | Liskeard, South West | — |
| 9 | Preston CofE Primary School Period 202425 | 112.0 | Academy · Day | Yeovil, South West | Outstanding |
| 10 | Marshfield Church of England Primary School Period 202425 | 112.0 | State · Day | Chippenham, South West | — |
| 11 | Lostwithiel School Period 202425 | 112.0 | Academy · Day | Lostwithiel, South West | Good |
| 12 | Eastcombe Primary School Period 202425 | 112.0 | State · Day | Stroud, South West | Good |
| 13 | Meysey Hampton Church of England Primary School Period 202425 | 112.0 | State · Day | Cirencester, South West | Good |
| 14 | Ashchurch Primary School Period 202425 | 112.0 | State · Day | Tewkesbury, South West | — |
| 15 | All Saints Marsh CofE Academy Period 202425 | 112.0 | Academy · Day | Newton Abbot, South West | — |
| 16 | Stone with Woodford Church of England Primary School Period 202425 | 112.0 | Academy · Day | Berkeley, South West | — |
| 17 | Antony Church of England School Period 202425 | 112.0 | Academy · Day | Torpoint, South West | Good |
| 18 | Widcombe CofE Junior School Period 202425 | 112.0 | Academy · Day | Bath, South West | — |
| 19 | Westbury Park School Period 202425 | 112.0 | Academy · Day | Bristol, South West | — |
| 20 | Awliscombe Church of England Primary School Period 202425 | 112.0 | State · Day | Honiton, South West | Good |
| 21 | St Levan Primary School Period 202425 | 112.0 | State · Day | Penzance, South West | Good |
| 22 | Landscove Church of England Primary School Period 202425 | 112.0 | Academy · Day | Nr Ashburton, South West | Good |
| 23 | Chagford Church of England Primary School Period 202425 | 112.0 | Academy · Day | Newton Abbot, South West | Good |
| 24 | Bromesberrow St Mary's Church of England Primary School Period 202425 | 112.0 | Academy · Day | Ledbury, South West | — |
| 25 | Rodmarton Primary School Period 202425 | 111.0 | State · Day | Cirencester, South West | — |