| 1 | Christow Primary School Period 202425 | 116.0 | Academy · Day | Exeter, South West | — |
| 2 | St Joseph's Catholic Primary School, Blackhall Period 202425 | 116.0 | Academy · Day | Hartlepool, North East | — |
| 3 | Addison Primary School Period 202425 | 115.0 | State · Day | London, London | — |
| 4 | Lowbrook Academy Period 202425 | 115.0 | Academy · Day | Maidenhead, South East | Good |
| 5 | Kimbolton St James CofE Primary School Period 202425 | 115.0 | State · Day | Leominster, West Midlands | — |
| 6 | Christ Church CofE School Period 202425 | 114.0 | State · Day | London, London | — |
| 7 | Saint Francis of Assisi Catholic Primary School Period 202425 | 114.0 | State · Day | London, London | — |
| 8 | Delamere CofE Primary Academy Period 202425 | 114.0 | Academy · Day | Tarporley, North West | Outstanding |
| 9 | Wincle CofE Primary School Period 202425 | 114.0 | State · Day | Macclesfield, North West | — |
| 10 | Barnes Primary School Period 202425 | 114.0 | State · Day | London, London | Outstanding |
| 11 | Wigmore Primary School Period 202425 | 114.0 | Academy · Day | Leominster, West Midlands | — |
| 12 | St Nicholas CofE VA Primary School Period 202425 | 114.0 | State · Day | Harpenden, East of England | — |
| 13 | Good Shepherd RC Primary School Period 202425 | 114.0 | State · Day | London, London | Outstanding |
| 14 | Hampden Gurney CofE Primary School Period 202425 | 114.0 | State · Day | London, London | Good |
| 15 | St Stephen's CofE Primary School Period 202425 | 114.0 | State · Day | London, London | Outstanding |
| 16 | Speldhurst Church of England Voluntary Aided Primary School Period 202425 | 114.0 | State · Day | Tunbridge Wells, South East | — |
| 17 | Longtown Community Primary School Period 202425 | 114.0 | State · Day | Hereford, West Midlands | — |
| 18 | Calveley Primary Academy Period 202425 | 114.0 | Academy · Day | Unknown, North West | — |
| 19 | Our Lady of Victories Catholic Primary School Period 202425 | 114.0 | State · Day | London, London | Good |
| 20 | Nicol Mere School Period 202425 | 114.0 | State · Day | Wigan, North West | Outstanding |
| 21 | St James & St John Church of England Primary School Period 202425 | 114.0 | State · Day | London, London | — |
| 22 | Duloe CofE VA Primary Academy Period 202425 | 114.0 | Academy · Day | Liskeard, South West | — |
| 23 | Trythall Community Primary School Period 202425 | 114.0 | State · Day | Penzance, South West | — |
| 24 | Barons Court Primary School and Nursery Period 202425 | 114.0 | Academy · Day | Westcliff-on-Sea, East of England | — |
| 25 | St Richard Reynolds Catholic Primary School Period 202425 | 114.0 | Academy · Day | London, London | Outstanding |